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Innovative preparation of Co@CuFe2O4 composite via ball-milling assisted chemical precipitation and annealing for glorious electromagnetic wave absorption

Journal 2023 · IF 4.8 · 30(3): 559-569 · 发表于 2023 年 1 月 14 日
作者: Feng Xing,Yin Pengfei,Zhang Limin,Sun Xiyuan,Wang Jian,Zhao Liang,Lu Changfang,Gao Zhihua,Zhan Yongxin
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摘要

To deal with the growing electromagnetic hazards, herein a Co@CuFe 2 O 4 absorbing agent with excellent impedance matching at thin thickness was obtained via an innovative route of ball-milling assisted chemical precipitation and annealing. The as-prepared composite possesses excellent interface polarization ability due to sufficient contact between CuFe 2 O 4 NPs and flat Co, and this compressed Co lamella can also provide sufficient eddy current loss. Moreover, the dipole polarization, electron hopping/conduction, and structural scattering also contribute to the broadband microwave absorption of the composite. Thus, the minimum microwave reflection loss achieves −35.56 dB at 12.93 GHz for 1.8 mm thickness, and the broadest efficient absorption bandwidth can reach 6.74 GHz for a thinner thickness of 1.72 mm. The preparation method reported here can be referenced as a new-type route to manufacture electromagnetic absorbers with outstanding performance.

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