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iRs-corrections induce potentially misjudging toward electrocatalytic water oxidation

Journal 2023 · IF 9.3 · 发表于 2023 年 1 月 12 日
作者: Shanfu Sun,Guopan Sun,Pengfei Cheng,Ruiqi Liu,Chunfu Zhang
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摘要

‘Outstanding’ electrocatalysts towards oxygen evolution reaction (OER) are springing up at present, to the extent that one questions if most nanomaterials are inherently highly active electrocatalysts . The answer is negative for certain easy-to-ignore data processing errors could lead to potential misjudgment of electrocatalytic activity. Combing through 100 highly cited papers (ESI 1% in Web of Science) concerning OER published in the last three years, the applications of uncompensated potential ( iR s )-correction rates are severely inconsistent. Herein, taking the benchmarks RuO 2 and IrO 2 as model catalysts, the authors investigated the effects of various iR s -correction rates on OER performance (overpotential, Tafel slope, and turnover frequency). The unanticipated discoveries may provoke a re-examination of those reported as ‘great’ OER electrocatalysts as well as help draw attention to iR s -correction rates in the field of electrocatalysis .

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