An economic, self-supporting, robust and durable LiFe5O8 anode for sulfamethoxazole degradation

Electrochemically activating peroxydisulfate (PDS) to degrade organic pollutants is one of the most attractive advanced oxidation processes (AOPs) to address environmental issues , but the high cost, poor stability, and low degradation efficiency of the anode materials hinder their application. Herein, an economic, self-supporting, robust, and durable LiFe 5 O 8 on Fe substrate (Fe@LFO) anode is reported to degrade sulfamethoxazole (SMX). When PDS is electrochemically activated by the Fe@LFO anode, the degradation rate of SMX is significantly improved. It is found that hydroxyl radicals (•OH), superoxide radical (O 2 •– ), singlet oxygen ( 1 O 2 ), Fe(Ⅳ), activated PDS (PDS*), and direct electron transfer (DET) reactions synergistically contribute to the degradation of SMX, which can realize the degradation of SMX in four possible routes: cleavage of the isoxazole ring, hydroxylation of the benzene ring, oxidation of the aniline group, and cleavage of the S–N bond, as evidenced by a series of tests of radicals quenching, electron paramagnetic resonance (EPR), linear sweep voltammetry (LSV) and liquid chromatograph mass spectrometer (LC-MS). Furthermore, Fe@LFO has good structural stability, excellent cyclability and low degradation cost, demonstrating its great potential for practical applications. This work contributes to a stable and effective anode material in the field of AOPs.