Piezoionic transfer effect in topological borophene-bismuthene derivative micro-leaves for robust supercapacitive electronic skins

To gain high performance in electrochemical device , exquisite accelerating ion-electron transfer is an effective way. Here, a topological idea is realized to design a micro-leave electrode by patterning borophene-bismuthene derivative. The inner bismuthene offers high conductive skeleton, intermediate BiOCl and Bi 2 O 3 derivative as ornament contribute to supercapacitive property, and the outer borophene layer not only boosts supercapacitive property, but also reserves the topological shape. Assisted by a hydrogel electrolyte on a flexible indium-doped tin oxide substrate, a robust pressure sensor is fabricated, in which a piezoionic transfer effect is demonstrated to induce fast ions extraction and migration kinetics among the topological micro-leaves. Then the specific capacitance of electrode increases by 2.483 times comparing with the micro-leaves without borophene. The resultant robust electronic skin sensor presents a comparable sensitivity of 1.60 kPa −1 in the tiny pressure range of ≈ 50–150 Pa, and sensitivity of 1.01 kPa −1 in 150 Pa-8.5 kPa, low detection limit as 0.59 Pa, fast response/recovery time (80/80 ms), wide detection range (∼220 kPa) and reliable capacitance retention of 97.92% even after 10000 cycles. This has been successfully used to monitor the physiological signals and illustrates potential application prospects in human-computer interaction.