Graphite carbon nitride loaded nitrogen-doped carbon and cobalt nanoparticles ternary photocatalyst for enhanced solar-driven hydrogen evolution

In this paper, we designed a composite photocatalytic system in which cobalt nanoparticles (Co NPs) are attached to nitrogen-doped carbon (N- d -C) and co-bonded to the surface of the noted photocatalyst graphite carbon nitride (g-C 3 N 4 ), showing an excellent photocatalytic hydrogen production . The bulk g-C 3 N 4 was formed in the first thermal treatment in air using melamine as a precursor. Subsequently, the secondary calcination under N 2 led to the synchronous fabrication of N- d -C/Co NPs and their combination with g-C 3 N 4 to form a novel ternary photocatalyst (g-C 3 N 4 /N- d -C/Co NPs). Co NPs exposed on the surface of the nanomaterials endowed much more reaction sites than g-C 3 N 4 for photocatalytic hydrogen production. Meanwhile, the embedded N- d -C provided an additional transfer approach for photocarriers. The as-prepared composite nanomaterials own a relatively high specific surface area of 97.45 m 2  g −1 with an average pore size of 3.83 nm. As a result, compared with pristine g-C 3 N 4 (∼25.35 μmol g −1  h −1 ), the photocatalytic performance was increased by over 10 times (∼270.05 μmol g −1  h −1 ). Our work gives a novel approach for highly active g–C 3 N 4 –based photocatalysts in the field of photocatalysis .