Preparation and formation mechanism of Cr-free spinel-structured high entropy oxide (MnFeCoNiCu)3O4

In this work, two Cr-free high entropy oxides (HEOs), an equimolar (MnFeCoNiCu) 3 O 4 and a non-equimolar (Mn 0.272 Fe 0.272 Co 0.272 Ni 0.092 Cu 0.092 ) 3 O 4 have been synthesized by a solid-state reaction method. The reaction sequence and electrical conductivity were also studied for these two HEOs. It is demonstrated that a rock-salt phase containing a solid solution of NiO and CuO appears in the synthesizing process of (MnFeCoNiCu) 3 O 4 , which is ascribed to the incomplete solubilization of rock-salt phase in the spinel phase. For (Mn 0.272 Fe 0.272 Co 0.272 Ni 0.092 Cu 0.092 ) 3 O 4 , a single spinel phase (Fd-3m) is obtained at 750 °C, which is much lower than that of the (MnFeCoNiCu) 3 O 4 sample. Furthermore, Mn, Fe, Co, Ni elements exist in the chemical states of +2 and + 3, and Cu exists in Cu 2+ state. The electrical conductivity of (Mn 0.272 Fe 0.272 Co 0.272 Ni 0.092 Cu 0.092 ) 3 O 4 is approximately 15.77 S cm -1 at 800 °C, which is nearly three times higher than that of the (MnFeCoNiCu) 3 O 4 sample.