摘要
Designing a photoelectrochemical (PEC) biosensor with preponderant sensitivity and anti-interference is a challenge for detecting small molecules in real samples with complex matrices . To this end, the Bi 2 O 3 /CuBi 2 O 4 was synthesized in one step to enhance visible light's absorption ability, transferring the interfacial carrier's efficiency, a high-active Z-scheme heterojunction , and a photocathode biosensor was proposed. For the first time, we used the density functional theory to verify a Z-scheme transfer pathway of photogenerated electrons in Bi 2 O 3 /CuBi 2 O 4 and the energy band structure of Bi 2 O 3 and CuBi 2 O 4 , respectively. Bi 2 O 3 /CuBi 2 O 4 -based PEC biosensor was developed for competive immunoassay of small molecular, aflatoxin B1 (AFB1) as an example, resulting in a low detection limit of 297.4 fg/mL and a linear range of 1.4 pg/mL-280 ng/mL in urine, water, peanut, and wheat samples. Using spiked experiments, the satisfied repeatability, reproducibility, stability, and specificity of the Bi 2 O 3 /CuBi 2 O 4 -based PEC biosensor indicated a promise for application in health care, the environment, and food.
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