Efficient conversion of CO2 into cyclic carbonates under atmospheric by halogen and metal-free poly(ionic liquid)s

A novel series of halogen free, hydroxyl group containing poly(ionic liquid)s (PILs) was first synthesized from glycerol dimethyl acrylate (GDA) and 1-vinyl imidazole (1-VIM) through free radical polymerization , follow by an alkylation step and an ion-exchange procedure to form the final imidazolium hydrogen carbonate heterogenous catalyst poly(HCO 3 -OH- n ). The chemical and physical properties were investigated by varying the monomer ratio between GDA and 1-VIM. Among them, poly (HCO 3 -OH-2) exhibited the highest catalytic activity for CO 2 cycloaddition, with the yield of chloropropene carbonate 90% under mild conditions (80 °C, 0.1 MPa, 12 h, 0.15 g catalyst for 32 mmol epichlorohydrin) in the absence of any cocatalyst, metal or solvent. A range of substrates with good to excellent yields under atmosphere was obtained. The poly(HCO 3 -OH- n ) catalyst is collectable and still remains acceptable catalytic activity after six runs. Finally, a preliminary kinetic is calculated on the basis of poly(HCO 3 -OH-2) with the activation energy value of 79.5 kJ·mol −1 . This study highlights that the poly(HCO 3 -OH- n ) enable to reach efficient CO 2 conversion under mild conditions.