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PTFE-Modified Mn-Co-Based Catalytic Ceramic Filters with H2O Resistance for Low-Temperature NH3-SCR

Journal 2022 · IF 3.889 · 14(9): 5353 · 发表于 2022 年 4 月 29 日
作者: Kun Li,Tao Zhou,Xinqiang Xu,Changye Han,Hua Zhang,Jiang Jin
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摘要

Mn-Co-based catalysts were loaded to ceramic filters element by impregnation for the coprocessing of dust and nitrogen oxide (NOx) in flue gas. The influence of the Mn/Co ratio and loading on the catalytic performance was investigated. The Mn-Co-based catalytic ceramic filter with a Mn/Co molar ratio of 2/1 can achieve 99% NO conversion by selective catalytic reduction of NOxwith NH3(NH3-SCR) in the temperature range of 100−180 °C, but its resistance to H2O was relatively poor. The filter element was modified by PTFE to improve the H2O resistance. After modification, the catalytic ceramic filter showed superior resistance to H2O and SO2at low temperatures (100–180 °C) and satisfactory self-cleaning performance.Keywords:NH3-SCR;catalytic ceramic filter;PTFE-modified;H2O resistance

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