Embedding indium nitride at the interface of indium-oxide/indium-zinc-sulfide heterostructure with enhanced interfacial charge transfer for high photocatalytic hydrogen evolution

Enhancing the interfacial charge carriers transfer efficiency is important for designing photocatalysts with excellent hydrogen evolution performance. In this work, we have successfully constructed a In 2 O 3 @InN/ZnIn 2 S 4 ternary heterostructure by embedding InN at the interface of thin-layered ZnIn 2 S 4 and tubular In 2 O 3 derived from metal-organic frameworks (MOFs) nanorods for the first time. The InN can not only adjust the energy band structure of In 2 O 3 , but also boost the photogenerated charge carriers transfer at the interface of In 2 O 3 and ZnIn 2 S 4 . The optimum photocatalytic hydrogen evolution rate of In 2 O 3 @InN/ZnIn 2 S 4 composite reaches 275 µmol/h (50 mg of catalyst) under simulated sunlight irradiation, which is obviously higher than pure In 2 O 3 (12.5 times), ZnIn 2 S 4 (2.5 times) and binary In 2 O 3 /ZnIn 2 S 4 (1.8 times) photocatalysts. This work can offer a meaningful strategy to promote the interfacial charge separation in the heterostructure for excellent photocatalytic hydrogen evolution activity.