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La0.8Sr0.2MnO3 Perovskite Catalysts Prepared by Different Methods for CO Oxidation

Journal 2022 · IF 2.936 · 152(12): 3843-3852 · 发表于 2022 年 2 月 24 日
作者: Huang Xuehui,Yang Na,Li Xiaobo,Pan Hongyun,Song Xiaozhan,Chang Yu
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摘要

La 0.8 Sr 0.2 MnO 3 (LSM) catalyst has been successfully prepared by solid phase method (G-LSM-T), sol–gel method (C-LSM-T) and molten salt method (S-LSM-T), using as-prepared MnCO 3 microspheres as templates, respectively. It was shown that the S-LSM-550 catalyst presented well-formed perovskite structures, large specific surface area (49.65m 2 /g) and promising catalytic activity in CO oxidation, which T 50 and T 90 for CO conversion over fresh S-LSM-550 were 145.14 °C and 170.73 °C. The S-LSM-550 calcined at 550 °C for 2 h exhibited excellent thermal stability and catalytic activity compared with the samples prepared by solid phase method and sol–gel method. Its superior catalytic performance could be greatly attributed to its stable microstructure, high surface Mn 4+ /Mn 3+ molar ratio and more available surface adsorbed oxygen species. Graphical Abstract

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