Enhanced H2 production from steam gasification of biomass by red mud-doped Ca-Al-Ce bi-functional material

The sorption-enhanced steam gasification of biomass (SESGB) using CaO-based materials is considered as a promising method for H 2 production. Ca-Al-Ce material has been reported as a good bi-functional material in SESGB process. Red mud is a solid waste in aluminium industry with large yield, which is rich in Fe 2 O 3 . In this work, a red mud-doped Ca-Al-Ce bi-functional material was prepared by wet-mechanical mixing method for H 2 production from SESGB. The CO 2 capture, H 2 production, and tar reduction performances during SESGB process using the red mud-doped Ca-Al-Ce bi-functional material were studied. The results show that the optimum addition amount of red mud in the bi-functional material is 5 wt%. After 20 SESGB cycles, the H 2 concentration using the red mud-doped Ca-Al-Ce material achieves 65.1 vol%, which is 82.4% higher than that using Ca-Al-Ce material. Besides, with the addition of red mud in the bi-functional material, the tar, residue char yields and CO 2 concentration decrease by 25.2%, 8.6% and 52.2%, respectively. Fe 2 O 3 in the red mud reacts with CaO to form Ca 2 Fe 2 O 5 in the 1st cycle, and Ca 2 Fe 2 O 5 is stable during 20 cycles, which is beneficial for the generation of oxygen vacancy. The oxidation states of Fe species in the material increase with the number of SESGB cycles, thus the catalytic effects on water gas shift reaction and tar reduction are promoted. The red mud addition is the key factor that results in high H 2 production, CO 2 capture and tar reduction performances, so the red mud-doped Ca-Al-Ce material appears promising for SESGB.