Sugarcane cellulose-based composite hydrogel enhanced by g-C3N4 nanosheet for selective removal of organic dyes from water

The effective removal of toxic dyes from aqueous solution is of great significance for environmental protection. Herein, an eco-friendly sugarcane cellulose (SBC)/sodium carboxymethylcellulose (CMC-Na) adsorbent reinforced with carbon nitride (g-C 3 N 4 ) was successfully prepared via a facile sol-gel method. The resulting gel-like adsorbent or composite hydrogel was comprehensively characterized with FTIR, SEM, EDS , TGA analysis. The adsorption behaviors of the adsorbent in the removal of methylene blue (MB) were systematically investigated. Results showed the pseudo-second-order kinetic model and Langmuir model described adsorption process accurately with the maximum adsorption capacity of 362.3 mg g −1 , indicating that adsorption behavior is a monolayer chemical adsorption. Moreover, the composited hydrogel displayed excellent adsorption selectivity on MB/MO or MB/RhB mixed dyes. In addition, adsorbent showed great stability and reusability with almost no loss in adsorption capacity after 7 cycles. Due to the facile preparation process and outstanding mechanical properties, as well as high recyclability, g-C 3 N 4 @SBC/CMC has great potential in wastewater treatment.