Efficient removal of mefenamic acid and ibuprofen on organo-Vts with a quinoline-containing gemini surfactant: Adsorption studies and model calculations

To pursue the adsorptivity of versatile vermiculite (Na-Vt)-based adsorbent targeted at emerging pharmaceuticals (mefenamic acid and ibuprofen, corresponding to MEA and IBP, respectively), a quinoline-based gemini surfactant (DHQU) with multi-functional groups is applied as modifier on Na-Vt. Enhanced hydrophobicity , enlarged interlayer space and decreased surface area of DHQU-Vt are obtained, whose modifier availability (the mole ratio of modifier intercalated to added) reaches up to 84.18% as characterized by FT-IR, XRD , TG-DTG, EA and BET analysis. Efficient adsorption of MEA/IBP (123.71/240.69 mg/g) is achieved under an extremely low DHQU dosage (0.2 CEC lower than the usual saturated dosage of organo-Vts), with all the processes fitting satisfactorily with pseudo-second order and Freundlich isotherm models accompanied by an exothermic nature. Acid pickling testifies a stable and reliable reusability process of DHQU-Vt even after 3 cycles. Multiple interactions (i.e., partition process, XH-π interaction, π-π interaction, π-π stacking and electrostatic interaction) are revealed and compared from not only characterization results, but also simulation of frontier orbital analysis, the adsorption configuration and bonding analysis: (i) The greater molecular flexibility of the adsorbate, the greater intra particle diffusion effect. (ii) π-π stacking between isolated aromatic rings is stronger than that between parallelly connected aromatic rings. (iii) The strength of multiple active sites provided by quinoline (CH-π, NH-π and π-π interactions) are comparable but weaker than electrostatic interaction/intra particle diffusion.