Role of Noncovalent Interactions on the Electrocatalytic Oxidation of Ethanol in Alkali Metal Hydroxide Solutions

Ethanol is considered to be one of the most promising fuels for fuel cells. However, ethanol fuel cells have a sluggish Faraday efficiency due to complex interactions between the electrolyte, electrode, and ethanol. Recent studies have further suggested that noncovalent interactions originated from the hydrated alkali metal cations and the adsorbed OHad at the Pt electrode surface also played an important role in the electron transfer. In this regard, the noncovalent interactions in different alkali metal hydroxide (AMH) solutions have been systematically investigated in this study, and it was observed that the noncovalent interactions could result in the occupation of the Pt electrode surface active sites and sluggish migration of ethanol molecules in the electrical double layer, significantly affecting the electro-oxidation efficiency. Further, it was concluded that the electro-oxidation efficiency in different AMH solutions followed the order of K+ > Na+ > Rb+ > Cs+ > Li+ due to the noncovalent interactions.