Improving Stability and Colloidal Dispersity of CsPbBr3@SiO2 Nanoparticles Based on In-Situ Synthesis in Entropy Ligands Functionalized SiO2 Nanoreactor

Perovskite nanocrystals (PNCs) have witnessed unprecedented development in optoelectronic fields over the past few years. However, their intrinsic ionic structural instability still dramatically hinders their practical applications. Reliably improving the stability of PNCs while retaining their colloidal dispersity remains a grand challenge. Herein, we report a new strategy whereby CsPbBr3nanoparticles are grown in situ in an entropy ligand-functionalized SiO2nanoreactor. Consequently, the as-obtained CsPbBr3@SiO2NPs show outstanding stability and colloidal dispersity in various non-polar solvents and have good solution processability, which are unattainable by conventional template-assisted methods.Keywords:perovskites nanocrystals;SiO2nanoreactor;entropy ligands;colloidal dispersity