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Enhancing the performance of CsPbIBr2 solar cells through zinc halides doping

Journal 2021 · IF 3.266 · 发表于 2021 年 9 月 21 日
作者: Zhu Chen,Qian Wang,Yinyan Xu,Lun Zhang,Akang Yang,Ru Zhou,Hongbo Lu,Mei Lyu,Jun Zhu
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摘要

B-site doping is an effective strategy to improve the performance of inorganic perovskite solar cells . Zinc halides (ZnX 2 , X I, Br, Cl) doped CsPbIBr 2 solar cells were prepared by simply introducing ZnX 2 salts into the precursor solution for one step spin-coating process. The doped inorganic perovskite films exhibit enhanced crystallinity and improved surface morphology . More over, the photoluminescence and single-carrier device characterizations confirm that the internal defect density of CsPbIBr 2 films decreases remarkably after ZnX 2 doping and the non-radiative recombination is suppressed. The CsPbIBr 2 solar cells based on the ZnI 2 doped films achieve a champion efficiency of 8.15%, outperforming that (6.93%) of the pristine counterpart.

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