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Solvothermal synthesis of nitrogen-doped MXene quantum dots for the detection of alizarin red based on inner filter effect

Journal 2021 · IF 4.889 · 发表于 2021 年 8 月 12 日
作者: Fanyong Yan,Jingru Sun,Yueyan Zang,Zhonghui Sun,Hao Zhang,Jinxia Xu,Xiang Wang
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摘要

MXene quantum dots (MQDs) derived from MXene with photoluminescent properties have attracted considerable attention. Herein, nitrogen-doped MQDs (N-MQDs) were constructed by a solvothermal method using Ti 3 C 2 MXene as precursors and o-phenylenediamine (oPD) as the nitrogen source. The morphology, element composition and optical properties of N-MQDs were investigated by transmission electron microscope (TEM), X-ray photoelectron spectroscopy (XPS) and spectroscopy etc. The obtained N-MQDs are dispersed quasi-spherical nanoparticles , mainly composed of carbon, oxygen and nitrogen, with yellow fluorescence at 580 nm and quantum yield of 5.42 %. In further, N-MQDs can detect Alizarin Red (ARS) based on inner filter effect (IFE) with linear range and detection limit of 0–80 μM and 1.21 μM, respectively. N-MQDs can detect ARS in real water samples, and were expected to have further applications in the fields of environmental monitoring and biosensing.

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