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Heat Capacity, Density, Vapor Pressure, and Enthalpy of Vaporization of Propyl Cinnamate

Journal 2021 · IF 2.694 · 发表于 2021 年 7 月 20 日
作者: Linmao Tang,Yuan Guo,Zuoxiang Zeng,Weilan Xue
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摘要

The density and liquid heat capacity of propyl cinnamate were measured in the temperature range from 290.15 to 503.15 K by a pycnometer and automatic adiabatic calorimeter and correlated with temperature by the linear equation and quadratic polynomial, respectively. Vapor pressure data of propyl cinnamate were determined by the ebulliometric method at 419.15–559.15 K, and they are in accordance with the Antoine equation. The vaporization enthalpy ΔvapH (Tb) of propyl cinnamate at normal boiling point was attained based on the Clausius–Clapeyron equation. The standard enthalpy of vaporization ΔvapH (298.15 K) was calculated by the Othmer method and verified by the Watson relation.

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