Finding an efficient far-red-emitting CaMg2La2W2O12:Mn4+ phosphor toward indoor plant cultivation LED lighting

The development of high-brightness far-red-emitting phosphors with emission wavelength within 650–750 nm is of great significance for indoor plant cultivation light-emitting diode (LED) lighting. Herein, we demonstrate a novel efficient far-red-emitting phosphors CaMg 2 La 2 W 2 O 12 :Mn 4+ (abbreviated as CMLW:Mn 4+ ) toward application in plant cultivation LEDs. Interestingly, the CMLW:Mn 4+ phosphors show a broad excitation band in the 250–600 nm spectral range with two peaks at 352 and 479 nm, indicating they could be efficiently excited by near-ultraviolet and blue light. Under 352 nm excitation, the CMLW:Mn 4+ phosphors exhibit an intense far-red emission band in the wavelength range of 650–800 nm peaking at 708 nm, corresponding to the 2 E g  →  4 A 2g transition of Mn 4+ ions. Mn 4+ doping concentration-dependent luminescence properties are studied in detail, and the concentration quenching mechanism is also investigated. Particularly, the internal quantum efficiency of CMLW:Mn 4+ phosphors reaches as high as 44%, and their PL spectra match well with the absorption spectrum of phytochrome P FR (P FR stands for far-red-absorbing form of phytochrome). Furthermore, a prototype LED device is fabricated by coating the as-prepared CMLW:0.8%Mn 4+ phosphors on a 460 nm blue LED chip, which produces bright far-red emissions upon 20–300 mA driving currents. This work reveals that the newly discovered far-red-emitting CMLW:Mn 4+ phosphors hold great potential for application in indoor plant cultivation.