A facile strategy synthesized PtRhNi truncated triangle nanoflakes with PtRh-rich surface as highly active and stable bifunctional catalysts for direct methanol fuel cells

Committed to improving the utilization efficiency of Pt atoms and accurately controlling the morphology and composition of nanocatalysts to boost the Pt-based catalyst performance has become the focus of research. Herein, the PtRhNi truncated triangular nanoflakes (TA-NFs) catalyst with a unique PtRh-rich surface structure was successfully prepared by an effective one-pot synthetic method based on the galvanic replace reaction. The freestanding 2D nanostructure of PtRhNi TA-NFs, intrinsically possessing much high specific surface area and surface atomic, and the PtRh-rich characteristics of the surface is undoubtedly the most feasible model to simultaneously achieve high atom utilization. Benefiting from this novel structure, the as-obtained PtRhNi TA-NFs nanocatalyst exhibits excellent performance for ORR and MOR, delivering a mass activity of 0.92 A mg pt -1 for ORR, which is 2.03, 1.64, and 6.9-fold higher than that of PtRhNi nanoparticls (NPs), PtNi truncated triangle nanoflakes (TA-NFs) and commercial Pt/C, respectively. In addition, after 20 k cycles ADT test, PtRhNi TA-NFs show only 10 mV negative shift of half-wave potential and retain 70% of initial value of mass activity. Furthermore, a mass activity is 1.28 A mg pt −1 is achieved after applying this unique nanocatalyst for MOR, which is 1.28,1.5, and 2.6 times higher than that of PtRhNi NPs, PtNi TA-NFs and Pt/C, respectively. Impressively, the PtRhNi TA-NFs nanocatalyst shows an ultrahigh stability even after 2 k cycles ADT measurement in acid solution, and the mass activity is only drop 2% of initial value. This work provides a new strategy to synthesis high-performance of bifunction Pt-based electrocatalyst for ORR and MOR fuel cells.