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Dual-sensitized modification engineering with enhanced photocatalytic degradation for organic dye

Journal 2021 · IF 2.478 · 32(14): 19380-19389 · 发表于 2021 年 6 月 30 日
作者: Zhao Yingying,Zhang Jiejing,Fu Wuyou
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摘要

Organic pollutant is an environmentally harmful and ubiquitous aquatic pollutant with extensive production and application. In this study, a unique novel TiO 2 -based dual-sensitized heterojunction photocatalyst (PbS/CdS/TiO 2 ) was successfully obtained by one step hydrothermal method, chemical bath deposition (CBD) method and ionic layer adsorption and reaction (SILAR) method. Scanning electron microscopy, X-ray photoelectron spectroscopy, transmission electron microscopy and energy dispersive spectrometer characterized the composition. PbS/CdS was successfully decorated on the surface of TiO 2 nanosheet array. As a stable catalyst with wide-spectrum (300–800 nm) optical response, excited electron–hole pairs of PbS/CdS/TiO 2 could apply in degrading organic pollutants. Successfully, the degradation efficiency of PbS(5 C)/CdS(30 min)/TiO 2 nanocomposites reached 99.9% under visible light, which was 5 times over pure TiO 2 . This ternary heterostructured materials will be well-promising photocatalysts.

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