The effective adsorption of tetracycline onto MoS2@Zeolite-5: Adsorption behavior and interfacial mechanism

The agglomeration and limited number of marginal adsorption sites have always been the restrictive factors for nano-MoS 2 adsorption performance. In this study, modified zeolite supported nano-MoS 2 (MoS 2 @Zeolite) with multiple adsorption sites was synthesized by combining ultrasonic and hydrothermal method, and utilized for tetracycline (TC) removal. MoS 2 @Zeolite-5 exhibits the best adsorption performance with a maximum saturation adsorption capacity of 396.70 mg g −1 (35 ℃). Meantime, MoS 2 @Zeolite-5 maintains a stable adsorption performance, which only decreased by 8.17% after four regeneration experiments. The structure characteristics and adsorption mechanism of adsorbents were also systematically investigated. The contact angle, crystal structure, micro-morphology analyses prove that modified zeolite plays the roles of enhancing the hydrophilia, restricting the growth of MoS 2 along C-axis, and exposing more adsorptive sites of MoS 2 . The Pseudo-second order kinetics is suitable for the model adsorption process and the adsorption process is endothermic. The adsorption mechanism of composites mainly relied on the chelation by Mo and electrostatic interaction. Furthermore, the effect of H-bonding and π-π action also existed. This study confirms that MoS 2 @Zeolite-5 is an efficient, stable, and promising adsorbent to treat TC-pollution of pharmaceutical wastewater.