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Flexible foam carbon/graphene oxide/Schiff base polymer-derived carbon/polyaniline for high-performance supercapacitor

Journal 2021 · IF 2.817 · 27(6): 2639-2647 · 发表于 2021 年 4 月 10 日
作者: Guo Yufei,Su Jianpo,Yang Han,Gu Fengling,Song Yonghai,Zhu Yongmei
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摘要

Here, a flexible electrode based on three-dimensional melamine foam-derived macroporous carbon (3D-FC) loading graphene oxide (GO), Schiff base polymer (SPB) foam-derived carbon (CNDS), and polyaniline (PANI) arrays are employed for supercapacitors. The commercial melamine foam is prepared into ultralight and flexible 3D-FC by high-temperature carbonization, and then the GO is uniformly distributed into 3D-FC to form 3D-FC/GO, which avoid the aggregation of GO. The SPB foam is grown on 3D-FC/GO and subsequently is transformed into CNDS by carbonization for loading PANI. The uniformly distributed GO connected the fibers of 3D-FC to improve the electrical conductivity. The macropores of 3D-FC/GO/CNDS/PANI enhance the mass transfer. The PANI is vertically arrayed on 3D-FC/GO/CNDS to form flexible 3D-FC/GO/CNDS/PANI. The as-prepared 3D-FC/GO/CNDS/PANI as electrode materials exhibits a rapid electron transport and good performance with a specific capacitance of 2814.5 F g −1 at the current density of 0.5 A g −1 .

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