Electrochemical synthesis of FeNx doped carbon quantum dots for sensitive detection of Cu2+ ion

A novel strategy was developed to fabricate FeN x -doped carbon quantum dots (Fe-N-CQDs) to detect Cu 2+ ions selectively as a fluorescence probe. The Fe-N-CQDs were synthesized by an efficient electrolysis of a carbon cloth electrode, which was coated with monoatomic iron-anchored nitrogen-doped carbon (Fe-N-C). The obtained Fe-N-CQDs emitted blue fluorescence and possessed a quantum yield (QY) of 7.5%. An extremely wide linear relationship between the Cu 2+ concentration and the fluorescence intensity was obtained in the range from 100 nmol L −1 to 1000 nmol L −1  (R 2  = 0.997), and the detection limit was calculated as 59 nmol L −1 . Moreover, the Fe-N-CQDs demonstrated wide range pH compatibility between 2 and 13 due to the coordination between pyridine nitrogen and Fe 3+ , which dramatically reduced the affection of the protonation and deprotonation process between H + and Fe-N-CQDs. It is notable that the Fe-N-CQDs exhibited a rapid response in Cu 2+ detection, where stable quenching can be completed in 7 s. The mechanism of excellent selective detection of Cu 2+ was revealed by energy level simulation that the LUMO level of Fe-N-CQDs (−4.37 eV) was close to the redox potential of Cu 2+ , thus facilitating the electron transport from Fe-N-CQDs to Cu 2+ .