Highly efficient photoelectrochemical removal of atrazine and the mechanism investigation: Bias potential effect and reactive species

In this work, efficient photoelectrochemical (PEC) removal of atrazine, one of the most widely used chemical herbicides in the world, was obtained by adjusting the bias potential applied on the photo-anode, and the optimal atrazine removal efficiency reached 96.8% at the potential of 0.2 V vs . SCE in 2 h with the reaction rate constant of 1.72 h −1 . The results indicated at the optimal potential, the separation efficiency of photo-generated holes and electrons was the highest with the lowest electron transfer resistance. Mechanism investigation revealed that superoxide radicals, hydroxyl radicals and holes all contributed to atrazine degradation, and the bias potential on the photo-anode could influence atrazine removal efficiency by changing the generation amount and distribution of the reactive oxygen species (ROS). It was presumed the nucleophilicity of superoxide radical played an important role in atrazine dechlorination , leading to the enhanced removal efficiency. However, the bias potential did not show obvious influence on the degradation intermediates of atrazine in the PEC system compared with that in photocatalytic oxidation , since it was actually an electro-assisted photocatalytic process in the potential range investigated. The work will provide fundamental basis for establishing efficient PEC system for pollutant remediation experimentally and theoretically.