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The effect of Al3+ doping on the infrared radiation and thermophysical properties of SrZrO3 perovskites as potential low thermal infrared material

Journal 2021 · IF 8.203 · 发表于 2021 年 3 月 10 日
作者: Enbo Li,Wen Ma,Peng Zhang,Chennan Zhang,Yu Bai,Hongxia Liu,Shufang Yan,Hongying Dong,Xiangfeng Meng
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摘要

A series of Al 3+ -doped SrZrO 3 perovskite powders with low infrared emissivity were prepared. The doping-effect of Al 3+ on infrared radiation ability and thermophysical properties was investigated in detail by theoretical and experimental methods. As a result, Al 3+ -doped SrZrO 3 perovskite's infrared emissivity is related to its electronic structure and particle morphology . It can be adjusted by the Al 3+ -doped concentration. The SrZr 0.86 Al 0.14 O 2.935 powder with stronger electronic conductivity and flake particles has the lowest infrared emissivity with 0.256 in 3-5 μm waveband at 590 °C and 0.383 in 8-14 μm waveband at 550 °C. Al 3+ -doped SrZrO 3 perovskites still maintain ideal thermal stability and low thermal conductivity above 800 °C. Base on both low infrared emissivity and thermal conductivity, Al 3+ -doped SrZrO 3 tablets exhibited weaker thermal radiation intensity in the high-temperature condition and might be the potential low thermal infrared materials servicing under extreme temperature in the future.

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