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Superior compatible interface and non-conductive two dimensional(2D) Co2(OH)2BDC nanosheets enabled the robust anti-corrosion and anti-friction performance epoxy coating system

Journal 2021 · IF 5.161 · 发表于 2021 年 2 月 9 日
作者: Hua-Rong Zhao,Zan Liu,Zhi-Lin Cheng
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摘要

The interfacial issue of nanomaterials-filled epoxy coating has seriously restrained its ongoing progress in actual application. In this paper, we reported a novel design for the robust anti-corrosion and anti-friction performance epoxy coating system based on the self-synthesized 2D Co 2 (OH) 2 BDC nanosheets with the native compatible interface compatibility and non-conductivity. The composite epoxy coatings(EP) were intensively characterized by a series of spectral instruments. The influence of the filling content of 2D Co 2 (OH) 2 BDC nanosheets to the interface structure of epoxy coating was probed by the microcosmic change. Lastly, the anti-corrosive, mechanical and tribological behaviors of the composite epoxy coatings were extensively investigated. At the optimal filling content of 0.6 wt.%, the low frequency impedance modulus of the 2D Co 2 (OH) 2 BDC/EP was increased by about 2 orders of magnitude relative to the neat epoxy coating. Moreover, the friction coefficient of the 2D Co 2 (OH) 2 BDC/EP was decreases by 20 % due to the layered structure of nanosheets derived from the weak van der Waals force, while the hardness and Young's modulus were separately increased by 41 % and 83.3 % as a result of the better compatibility and dispersion in epoxy matrix to a certain degree.

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