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Solubility and stability of diamond in cobalt under 5 GPa

Journal 2020 · IF 2.65 · 发表于 2020 年 11 月 1 日
作者: Yi Tian,Junpu Wang,Jiawei Zhang,Shixue Guan,Lu Zhang,Binbin Wu,Yuzhu Su,Mengyang Huang,Li Zhou,Duanwei He
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摘要

The stability and solubility of diamond in cobalt at a pressure of 5 GPa was investigated. At temperatures ranging from 1000 °C and 1350 °C, diamond can be dissolved in cobalt without graphitization . Meanwhile, the solubility of single diamond crystals in cobalt was measured at 5 GPa and temperatures of up to 1300 °C through weight analysis, and it was found to increase with the increase in temperature. The morphological changes of the diamond crystals after high-pressure and high-temperature (HPHT) treatments were observed using a scanning electron microscope . The resulting quantitative data and morphology analysis enabled the construction of a scheme for the morphological evolution of diamond crystals during their dissolution in cobalt at HPHT. The diamond formation process in cobalt solvent is discussed in relation to the dynamic equilibrium.

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