Effective degradation of aqueous carbamazepine on a novel blue-colored TiO2 nanotube arrays membrane filter anode

The effective electrochemical oxidation of aqueous carbamazepine (CBZ) using a novel blue-colored TiO 2 nanotube arrays (BC-TiO 2 NTA) membrane filter anode was studied. The BC-TiO 2 NTA was characterized using SEM, TEM, BET, mercury intrusion porosimetry, XPS, XRD, CV, and LSV. The BC-TiO 2 NTA had reserved pore structure, formed mesopores, specific and electroactive surface areas of 2.01 m 2 g −1 and 9.32 cm 2 cm −2 , respectively. The oxygen evolution potential was 2.61 V vs. SCE. CBZ could be degraded by OH, SO 4 − and O 2 − on BC-TiO 2 NTA in accordance to pseudo-first-order kinetic, which was greatly enhanced in flow-through mode. The optimal kinetic rate constant of CBZ degradation of 0.403 min −1 was achieved at 3 mA cm −2 , while energy consumption per order was 0.086 kW h m −3 . The mineralization efficiency and mineralization current efficiency were 50.8 % and 9.5 % at 180 min, respectively. The presence of Cl − (0.3−3 mM) accelerated electrochemical degradation of CBZ, while NO 3 − (0.1−2 mM) inhibited the reaction. Based on density functional theory calculation and UPLC-Orbitrap-MS/MS measurement, we found that electrochemical degradation of CBZ was initialized by cleavage of −CONH 2 group and attack of OH on the olefinic double bond of the central heterocyclic ring.