MoS2 as highly efficient co-catalyst enhancing the performance of Fe0 based electro-Fenton process in degradation of sulfamethazine: Approach and mechanism

Molybdenum sulfide (MoS 2 ) was for the first time used as a co-catalyst to enhance the performance of Fe 0 based heterogeneous electro-Fenton (Fe 0 -EF) process for the degradation of sulfamethazine (SMT), which was belonging to the sulfonamide family and extensively used as growth promoters and antibacterial drugs. Compared with Fe 0 -EF process, MoS 2 /Fe 0 -EF process could enhance the rate constant of SMT degradation 2 times under the optimal conditions of current 50 mA, MoS 2 dosage 0.02 g L -1 , Fe 0 dosage 0.224 g L -1 , and initial pH 4, in which SMT could be completely degraded within 10 min while 42% TOC could be achieved after 60 min reaction. The role of MoS 2 as co-catalyst in MoS 2 /Fe 0 -EF process and Fe 2+ /Fe 3+ cycle was supported by iron elemental analysis, transmission election microscopy (TEM) and X-ray photoelectron spectroscopy (XPS) characterizations. Owing to the characteristics of co-catalysis, MoS 2 could greatly facilitate the Fe 3+ /Fe 2+ recycle reaction by the exposed Mo 4+ active sites, which significantly promoted the decomposition of H 2 O 2 that generated in Fe 0 -EF system and improved the generation of hydroxyl radical. Besides, a possible degradation pathway of SMT was proposed and the stability of MoS 2 /Fe 0 -EF process for SMT removal and TOC mineralization was certified base on five consecutive runs. The real wastewater test and energy consumption and economic analysis confirmed its advantage and cost-effectiveness for application. In all, this study provides a new perspective for improving heterogeneous Fe 0 -EF process with MoS 2 for highly efficient and rapid degradation of antibiotics.