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Volumetric and viscometric properties of ternary solution of (piperazine +2-Amino-2-methyl-1-propanol + H2O) at T = (303.15–343.15) K

Journal 2020 · IF 5.065 · 发表于 2020 年 4 月 24 日
作者: Xiaojie Liu,Chunying Zhu,Taotao Fu,Youguang Ma
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摘要

The densities and viscosities of ternary solution of piperazine (PZ) + 2-Amino-2-methyl-1-propanol (AMP) + H 2 O were measured at P  = 101 kPa and T  = (303.15–343.15) K. The effects of temperature and concentration on the density and viscosity of ternary solution were investigated. The apparent molar volume ( V φ ), the limiting partial molar volume ( V φ 0 ), viscosity B -coefficient, Helper's constant and the free energies of activation per mole of solvent ( Δμ 1 0≠ ) and solute ( Δμ 2 0≠ ) were calculated from the density and viscosity, respectively. The solute-solute and solvent-solute interactions were analyzed from the volumetric and viscometric properties. The results show that the PZ has a destructive effect on the structure of mixed solvent.

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