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Reaction Mechanism Dominated by the Hard–Soft Acid–Base Theory for the Oxidation of CH2Cl2 and CH3Br over a Titanium Oxide-Supported Ru Catalyst

Journal 2020 · IF 3.573 · 发表于 2020 年 3 月 31 日

作者: Lirong Lv,Sheng Wang,Ya Ding,Lei Zhang,Yang Gao,Shudong Wang

研究领域化学催化反应环境科学

关键词氧化机制卤代挥发性有机化合物硬软酸碱理论二氧化钛钌催化剂

摘要

In this study, the divergent behaviors were elucidated for CH2Cl2 and CH3Br oxidation over TiO2 and Ru/TiO2. Possible reaction mechanisms were elucidated. It was concluded that the adsorption and activation of halogenated volatile organic compounds were strongly dependent on the hard–soft acid–base theory.

文献概览

影响因子 3.573 (2020)

阿拉丁产品 50

DOI 10.1021/acs.iecr.9b06964

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出版方 MDPI

类型 Journal

引用本文

作者

LL Lirong Lv第一作者中国科学院大连化学物理研究所, 大连市, 中国

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Reaction Mechanism Dominated by the Hard–Soft Acid–Base Theory for the Oxidation of CH2Cl2 and CH3Br over a Titanium Oxide-Supported Ru Catalyst

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