A Heat-Resistant Poly(oxyphenylene benzimidazole)/Ethyl Cellulose Blended Polymer Membrane for Highly Safe Lithium-Ion Batteries

A blended membrane based on poly(oxyphenylene benzimidazole) (PBI) and ethyl cellulose (EC) exhibits heat resistance and good electrochemical performance. The prepared blended polymer gel membranes show no visible dimensional change after being held at 350 °C for 30 min, whereas the polyethylene (PE) separator almost completely melts. In addition to excellent thermal stability, the self-supporting blended membranes also exhibit a uniform thermal distribution during the heating process from 60 to 200 °C. Additionally, the ionic conductivities of the PBI/EC blended membranes with different ratios are 1.24 mS cm–1 (1:1), 2.58 mS cm–1 (1:2), and 1.68 mS cm–1 (1:3), which are much higher than those of the PE separator (0.39 mS cm–1). Compared to that of the PE separator (113 mAh g–1), the cell with a separator of PBI/EC = 1:2 retained a discharge capacity of 131 mAh g–1 after 150 cycles at 0.5C. Meanwhile, the rate performance of the cell was also better than that of the PE separator, especially at high currents (5C). All of the results indicate that this blended polymer gel membrane with good thermal stability is expected to be applied to high-performance lithium-ion batteries.