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Exfoliated MoS2@C nanosheets as anode for sodium/potassium storage

Journal 2019 · IF 2.289 · 26(4): 1779-1786 · 发表于 2019 年 12 月 10 日
作者: Chen Zhi,Chen Suilong,Zhang Hanfu,Liu Mingqiang,Feng Zhjun,Li Xibao,Huang Juntong,Guo Di
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摘要

Due to high theoretical capacity (670 mA h g −1 ), MoS 2 can become a good application for energy storage. It is reported that the layer spacing of MoS 2 can be exfoliated, which improves Na + /K + insertion/extraction and promotes electron diffusion and ion transport. So, we obtained exfoliated MoS 2 nanosheets with the modification of a carbon layer, in order to form exfoliated MoS 2 @C nanosheets. With the analysis of XRD and TEM, it was found that the larger interlayer spacing was obtained. As the anodes for sodium ion batteries (SIBs), the exfoliated MoS 2 nanosheet electrode showed a high capacity (641 mA h g −1 at 50 mA g −1 ) and maintained a capacity of 214 mA h g −1 at 1000 mA g −1 after 400 cycles. Moreover, it was discussed as anode for potassium ion batteries (KIBs). It can be found that the electrode had 241 mA h g −1 at 100 mA g −1 after 20 cycles.

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