Levels of NP and BPA in the Pearl River Estuary, China: Fluctuations with Country Policy Changes over the Past 40 Years

Sediment cores were collected from four outlets in the Pearl River Estuary (Guangdong Province, China) and dated using the210Pb method to investigate the pollution history of the area due to its relatively stable sedimentation status and hydrographic conditions in recent decades. The ages of the sediment cores were dated over 40 years (1968–2015). The concentrations at the four outlets ranged from 2.21 to 48.52 ng g−1dw for nonylphenol and were non-detectable for 23.64 ng g−1dw for bisphenol A (BPA), which exhibited a decreasing trend from north to south as well as seaward. The fluxes (2.84 to 112.91 ng cm−2yr−1and non-detectable to 59.33 ng cm−2yr−1for nonylphenol and bisphenol A, respectively) stabilized in the 1980s to 1990s due to the construction of sewage treatment systems. The fluxes increased again in the 21st century, which reached a peak ca. 2010 but declined in recent years due to the establishment of regulations and the decreasing number of industrial enterprises. Fluctuations in the pollution composition coincided with industrial development and governmental policies.Keywords:nonylphenol;bisphenol A;dry mass sedimentation rates;historical trends;Pearl River Estuary