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Fabrication and adsorption properties of multiwall carbon nanotubes-coated/filled by various Fe3O4 nanoparticles

Journal 2019 · IF 2.195 · 30(20): 18802-18810 · 发表于 2019 年 9 月 30 日
作者: Zhao Ke,Xu Ting,Cao Jian,Yang Lili,Wei Maobin,Fan Hougang,Liu Huilian,Liu Chengyou,Liu Xiaoyan
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摘要

Carbon nanotubes-coated/filled by Fe 3 O 4 nanoparticles were successfully fabricated by a facile in-situ coprecipitation method at low temperature. The effects of the adding amounts of Carbon nanotubes (CNTs) on the morphology, structure, magnetic and adsorption properties of the nanocomposites were studied in detail. The XRD patterns showed that the sizes of Fe 3 O 4 nanoparticles in the nanocomposites could be well tuned from a few nanometers to a dozen nanometers. The SEM and TEM images revealed that different coverage density and composite mode had happened between CNTs and Fe 3 O 4 nanoparticles. All of the nanocomposites exhibited favorable superparamagnetic properties, and the saturation magnetization was affected by the average grain sizes and the loading amounts of Fe 3 O 4 nanoparticles. Strong magnetization and high dispersion of Fe 3 O 4 /CNTs nanocomposites implied the excellent adsorption capacity and recycle of nanocomposites in the practical application. The adsorption kinetics of methylene blue (MB) was well described by the pseudo-second-order kinetic model.

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