Co-modified MoO2 nanoparticles highly dispersed on N-doped carbon nanorods as anode electrocatalyst of microbial fuel cells

Cobalt-modified molybdenum dioxide nanoparticles highly dispersed on nitrogen-doped carbon nanorods (Co–MoO 2 /NCND), are synthesized from anilinium trimolybdate dihydrate nanorods, for the performance improvement of microbial fuel cell based on a mixed bacterial culture . Electrochemical measurements demonstrate that the as-synthesized Co–MoO 2 /NCND exhibits excellent electrocatalytic activity for the charge transfer on anode, providing the cell with a maximum power density of 2.06 ± 0.05 W m −2 , which is strikingly higher than the bare carbon felt anode (0.49 ± 0.04 W m −2 ). The excellent performance of Co–MoO 2 /NCND is ascribed to the increased electronic conductivity of carbon nanorods by N-doping, the high ability of MoO 2 to enrich electroactive bacteria, as demonstrated by high-throughput sequencing, and the enhanced activity of MoO 2 by Co-modifying toward redox reactions in electroactive bacteria. This report provides a new concept of anode electrocatalyst fabrications for the application of microbial fuel cells in electricity generation and wastewater treatment .