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Enhancing the cycling stability of Na-ion batteries by bonding MoS2 on assembled carbon-based materials

Journal 2019 · IF 0 · 发表于 2019 年 9 月 6 日
作者: Pin Song,Jun Di,Lixing Kang,Manzhang Xu,Bijun Tang,Jun Xiong,Jiewu Cui,Qingsheng Zeng,Jiadong Zhou,Yongmin He,Qundong Fu,Juan Peng,Shasha Guo,Bo Lin,Jingyu Zhang,Peng Meng,Zheng Liu
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摘要

Room temperature Na-ion batteries (SIBs) show great potential for use as renewable energy storage systems. However, the large-scale application of SIBs has been hindered by the lack of an ideal SIBs anode material. We synthesized MoS 2 on carbonized graphene-chitosan (G-C) using the hydrothermal method. The strong interaction between the MoS 2 and the G-C greatly improved the electron transport rate and maintained the structural stability of the electrode, which lead to both an excellent rate capability and long cycle stability. The G-C monolith was proven to enhance the electrical conductivity of the composites and served as a matrix for uniformly dispersing active MoS 2 nanosheets (NSs), as well as being a buffer material to adapt to changes in volume during the cycle. Serving as an anode material for SIBs, the MoS 2 -G-C electrode showed good cycling stability (527.3 mAh g −1  at 100 mA g −1 after 200 cycles), excellent rate capability, and a long cycle life (439.1 mAh g −1  at 1A g −1 after 200 cycles).

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