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Metal-organic frameworks derived N, S co-doped bimetal nanocomposites as high-performance electrodes materials for supercapacitor

Journal 2019 · IF 4.175 · 发表于 2019 年 8 月 22 日
作者: Qi Li,Liguo Yue,Li Li,Hui Liu,Wenqin Yao,Ning Wu,Longwen Zhang,Hao Guo,Wu Yang
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摘要

Nitrogen sulfur co-doped bimetal nanocomposites (NS-BNs) are prepared through vulcanization and annealing using bimetallic Ni/Co-MOF as a precursor. The nitrogen sulfur co-doped bimetal nanocomposites have abundant electroactive sites and redox reaction centres, which exhibit remarkable electrochemical performance as electrode materials for supercapacitor . The specific capacitance could reach 1529 F g −1 at a current density of 1 A g −1 and excellent cycle stability (retention rate of 89.29% after 10000 cycles). After the current density is expanded ten times, the specific capacitance can still reach 1069 F g −1 , indicating superior rate performance. Furthermore, the assembled asymmetric supercapacitor displayed a high energy density of 41.04 Wh kg −1 at power density of 750 W kg −1 . As a result, non-metal doped nanocomposites material has promised applications for electrochemical supercapacitors.

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