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Preparation and characterization of polymethyl methacrylate light-scattering material

Journal 2019 · IF 1.858 · 77(6): 3223-3235 · 发表于 2019 年 8 月 21 日
作者: Jiang Jingzhe,Wei Anqi,Li Jianping,Ji Yue,Qiang Huijun,Jiang Yan,Zhang Hongwen,Liu Hongbo
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摘要

In this paper, hydroxyl terminated polysiloxane was first prepared by ring-opening polymerization of octamethylcyclotetrasiloxane (D 4 ), which was then modified with acryloyl chloride to obtain acryloyloxy polysiloxane. A light-scattering material was synthesized by copolymerization of acryloyloxy polysiloxane and methyl methacrylate (MMA). The results showed that the transmittance of the material was 88% and the haze was 93% when the ratio of MMA to light-scattering agent was 100:1, the amount of initiator was 0.3%, and the post-polymerization temperature was 50 °C. The TGA data indicated that the material had excellent heat resistance. Therefore, it has a wide range of applications in the field of light-emitting diodes.

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