摘要
Poly(cyclotriphosphazene- co -4,4′-diaminodiphenyl ether) microspheres (PZA) was based on hexachlorocyclotriphosphazene (HCCP) and 4,4′-diaminodiphenyl ether (ODA). It was synthesized via one-step precipitation method. The PZA microspheres were characterized by FT-IR, XPS, zeta potential and SEM/EDS. Through experimental research, PZA microspheres had the optimal adsorption performance with pH value 3.5, contact time of 60 min, thorium(IV) ions concentration of 30 mg L −1 , and PZA microspheres of 10 mg. The maximum adsorption capacity of PZA microspheres for thorium(IV) was 29.04 mg g −1 . The adsorption process could be described by the quasi-second order kinetic model and simulated by the Langmuir isotherm equation.
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