Convenient Synthesis of 3D Fluffy PtPd Nanocorals Loaded on 2D h-BN Supports as Highly Efficient and Stable Electrocatalysts for Alcohol Oxidation Reaction

Fuel cells hold great promise for clean and sustainable energy, whereas their widespread commercialization strongly depends on the development of highly efficient and stable electrocatalysts. Herein, three-dimensional fluffy PtPd nanocorals (NCs) loaded on two-dimensional (2D) hexagonal boron nitride (h-BN) supports were successfully achieved by a simple one-step strategy based on ultraviolet (UV) laser-excited photochemical reaction. As for alcohol oxidation reaction, the h-BN/PtPd NCs with unique nanoporous surface provide more enhanced electrocatalytic performances than many previous nanocatalysts, owing to abundant active sites and plentiful charge-transfer channels formed on high electrode–electrolyte contact area. Especially, the mass activity of h-BN/PtPd NCs is about 962.8 mA mgPtPd–1 in methanol oxidation reaction in alkaline solution, which can be maintained at ∼274.9 mA mgPtPd–1 (28.6% of the initial one) even after a 5 × 104 s durability test. The present work not only offers an advanced electrocatalyst for long-term fuel cells but also provides a versatile route for construction of complex metallic nanocomposites on 2D supports, holding great potential for diverse energy-related applications.