Comparative study of three novel organo-clays modified with imidazolium-based gemini surfactant on adsorption for bromophenol blue

In this paper, an imidazolium-based gemini surfactant [C 14 -4-C 14 im]Br 2 was fabricated as modifiers of vermiculite, silica nanosheets (from acid treating vermiculite) and montmorillonite . The modified clays were characterized with FT-IR, XRD, TG, EA , SEM and Washburn capillary rise method and investigated regarding the adsorption capacity for bromophenol blue (BPB). These organo-clays under similar availability of modifier show efficient removal for BPB with the order: C 14 -4-C 14 im-Vt > C 14 -4-C 14 im-SiNSs > C 14 -4-C 14 im-Mt. The adsorption processes are discovered fitting pseudo-second-order kinetics and Langmuir isotherm models. The q max of organo-Vt, organo-SiNSs and organo-Mt calculated with Langmuir isotherm model are 400.19, 230.77 and 220.27 mg g −1 , respectively, which prove organo-clays with imidazolium surfactants acquiring superior adsorbability to other known adsorbents. The adsorption capacity get higher with lower pH value and perform a positive correlation with the wettability . It can be concluded that electrostatic and hydrophobic interactions paly critical roles during the process. C 14 -4-C 14 im-SiNSs possesses higher adsorption efficiency ( R  = 99.53% at pH = 2, C 0  = 200 mg L −1 ) noticeably. These provide some ideas for the use of imidazole-containing surfactants in modifying clays for contaminant treatment.