Establishing highly-efficient surface faradaic reaction in flower-like NiCo2O4 nano-/micro-structures for next-generation supercapacitors

As in the case of supercapacitors , spinel NiCo 2 O 4 shows the main drawbacks of objectionable pseudocapacitive mechanism, low-voltage polarization effect and confined ion-reaction dynamics, which result in constrained development, narrow work voltage, and low loading mass. Herein we combined two strategies to address these issues. The first one is to design the flower-like NiCo 2 O 4 through Ostwald ripening of ultrathin Ni-Co layered double-hydroxide petals. And the second one is to balance the asymmetrical capacitance for further promoting capacitive behavior. With rationally designing the nano-/micro-structures, flower-like NiCo 2 O 4 shows highly porous ultrathin petals interconnected with each other and massive interspaces between the petals. This unique microstructure endows flower-like NiCo 2 O 4 with rapid electrolyte ions diffusion and mass transfer reaction. Consequently, the flower-like NiCo 2 O 4 electrodes exhibit a high capacity of ∼350 C g −1 even the loading mass of up to 9 mg cm −2 . More importantly, the hybrid supercapacitors , assembled with flower-like NiCo 2 O 4 as cathode, deliver a high specific capacity of ∼85 F g −1 with capacitive ratio up to 74.3%, and a high working voltage of 1.55 V. The transformation of conventional battery-like materials into novel capacitive dominated materials through nano/micro-structural design and balance of asymmetrical capacitance is helpful to further understand the pseudocapacitive mechanism of transition metal oxides/sulfides and therefore will promote their practical application in next-generation of hybrid supercapacitors.