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Facile synthesis of three-dimensional porous carbon for high-performance supercapacitors

Journal 2019 · IF 4.175 · 发表于 2019 年 2 月 5 日
作者: Weidong Zhao,Yun Zhu,Litong Zhang,Yunlong Xie,Xiangrong Ye
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摘要

Porous activated carbon (PAC) with three-dimensionally (3D) interconnected structure has been successfully synthesized using sucrose and potassium hydroxide as carbon source and pore-forming agent, respectively. On account of its hierarchically porous structure and high specific surface area (1615 m 2  g −1 ), the synthesized porous carbon displays a maximal specific capacitance of 119 F g −1 at 1 A g −1 and a capacitance retention rate of 81.2% after 5000 cycles at 20 A g −1 in 1 M TEABF 4 /AN electrolyte. It also exhibits a maximal specific capacitance of 178 F g −1 at 0.5 A g −1 and a capacitance retention rate of 88.9% after 10000 cycles at 16 A g −1 in 1 M Na 2 SO 4 electrolyte. Moreover, the fabricated symmetric supercapacitor reveals a high energy density , 16.52 W h Kg −1 in 1 M TEABF 4 /AN and 15.78 W h Kg −1 in 1 M Na 2 SO 4 . Such an excellent supercapacitive performance implies that the prepared activated carbon with 3D interconnected porous structure could be potentially used for high performance energy storage device.

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