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Facile fabrication of Ag/PANI/g-C3N4 composite with enhanced electrochemical performance as supercapacitor electrode

Journal 2018 · IF 3.235 · 发表于 2018 年 12 月 18 日
作者: Jie Ma,Xue-Yu Tao,Shi-Xiang Zhou,Xiang-Zhu Song,Lin-Guo,Yao-Wang,Ya-Bo Zhu,Li-Tong Guo,Zhang-Sheng Liu,He-Liang Fan,Xian-Yong Wei
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摘要

Ag nanoparticles decorated Polyaniline (PANI)/graphitic carbon nitride (g-C 3 N 4 ) composite was fabricated as active electrode materials for supercapacitors via an in-situ oxidative polymerization. Morphology and structure of Ag/PANI/g-C 3 N 4 composite were investigated by scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared (FT-IR) and X-ray diffraction (XRD). The supercapacitive behavior of the electrode material was tested in a three electrode system using 1.0 M H 2 SO 4 electrolyte. The results indicated that the Ag/PANI/g-C 3 N 4 composite delivered a high specific capacitance of 797.8 F g −1 and an excellent capacitance retention of 84.43% after 1000 cycles at an applied current density of 1 A g −1 . Ragone plot was derived and compared which showed enhanced supercapacitive performance of Ag/PANI/g-C3N4. The composite should be ideal potential electrode materials for high-performance and effective supercapacitors.

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