Hydroxide Conduction Enhancement of Chitosan Membranes by Functionalized MXene

In this study, imidazolium brushes tethered by –NH2-containing ligands were grafted onto the surface of a 2D material, MXene, using precipitation polymerization followed by quaternization. Functionalized MXene was embedded into chitosan matrix to prepare a hybrid alkaline anion exchange membrane. Due to high interfacial compatibility, functionalized MXene was homogeneously dispersed in chitosan matrix, generating continuous ion conduction channels and then greatly enhancing OH−conduction property (up to 172%). The ability and mechanism of OH−conduction in the membrane were elaborated based on systematic tests. The mechanical-thermal stability and swelling resistance of the membrane were evidently augmented. Therefore, it is a promising anion exchange membrane for alkaline fuel cell application.Keywords:functionalized MXene;chitosan;anion exchange membrane;hydroxide conductivity;alkaline fuel cell