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Euonymus maackii Rupr. Seed oil as a new potential non-edible feedstock for biodiesel

Journal 2018 · IF 4.9 · 发表于 2018 年 10 月 9 日
作者: Ju-Zhao Liu,Qi Cui,Yu-Fei Kang,Yao Meng,Ming-Zhu Gao,Thomas Efferth,Yu-Jie Fu
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摘要

In this study, Euonymus maackii Seed oil (EMSO) was exploited and evaluated for the first time as a new non-edible oil feedstock for preparation of biodiesel . The EMSO yield was 41.06 ± 2.68 wt%. The fatty acid compositions of EMSO involved palmitoleic acid (2.01%), palmitic acid (14.5%), stearic acid (3.1%), oleic acid (49.8%), linoleic acid (29.3%), 11-Eicosenoic acid (0.1%) and arachidic acid (0.07%). Microwave-assisted transesterification with methanol provided a high conversion yield in short duration under low temperature. The 2.0 wt% of catalyst amount, 10:1 of methanol/oil molar ratio , 40 min of reaction time and 60 °C of temperature were found to be the optimum process conditions for the maximum biodiesel yield of 94.74 ± 2.09%. Using pseudo first-order kinetic model , the reaction rate constants were 2.145 × 10 2 , 3.550 × 10 2 and 6.447 × 10 2 min −1 for 40, 50 and 60 °C, respectively. The thermodynamic property for biodiesel preparation was determined as activation energy = 47.67 kJ/mol. The fuel properties of the biodiesel product were evaluated and comparable to ASTM D-6751 and EN 14214 standards. Overall, this study revealed and confirmed the potential of Euonymus maackii seed oil as the appropriate alternative feedstock for biodiesel production .

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