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Porous Organic Polymer from Aggregation-Induced Emission Macrocycle for White-Light Emission

Journal 2018 · IF 5.914 · 发表于 2018 年 9 月 27 日
作者: Zhen Wang,Sen Yan,Huang-Chen Cui,Guang Cheng,Hui Ma,Qing-Mei Zhang,Qing-Pu Zhang,Jun-Min Liu,Bien Tan,Chun Zhang
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摘要

A tetraphenylethylene-based oxacalixarene macrocycle (TOM) with high fluorescence quantum yield (70%) was used as monomer to construct a fluorescent macrocycle-based porous organic polymer (pTOM). With high surface area, specific pore size, and emissive properties, the blue-greenish fluorescent pTOM can be developed into white-light-emission materials by adsorbing guests of tris(bipyridine)ruthenium with complementary emission color by the Förster resonance energy transfer (FRET) effect.

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